%mem=16000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3
scf=(maxcyc=1000,conver=8,nosym)

ch3shf

-1 1
 C                 -0.73195000   -0.01828800    0.00003000
 H                 -0.68764600    0.51532500   -0.93467300
 H                 -0.71132900   -1.09643400    0.00035100
 H                 -0.68768700    0.51587300    0.93442200
 H                  1.88439900    1.27065000   -0.00000100
 S                  1.75505500   -0.07739500   -0.00000700
 F                 -2.60965800    0.01584800   -0.00001900

