%mem=16000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=8) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3
scf=(maxcyc=1000,conver=8,nosym)

ch3och3-sh

-1 1
 C                 -0.07096500    0.26695300   -0.04254000
 H                  0.10692300   -0.35138700   -0.90925300
 H                  0.09023700   -0.14381000    0.94114900
 H                 -0.18189900    1.33102800   -0.17026500
 O                  1.98469000    0.68806800   -0.05818800
 C                  2.64192500   -0.51882100    0.05838500
 H                  3.74858800   -0.40066700    0.05287700
 H                  2.41460300   -1.23784800   -0.76837800
 H                  2.40608400   -1.07214400    1.00209300
 H                 -2.59785000    0.60366400    1.02727400
 S                 -2.33062300   -0.17013600   -0.05031600

