%mem=16000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest) freq b3lyp/genecp
scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3
scf=(maxcyc=1000,conver=8,nosym)

ch3br-sch3-ts_6311+Gd

-1 1
 C                 -0.64550500   -0.03286700    0.00000800
 H                 -0.73266600    0.49848600    0.92955300
 H                 -0.71420900   -1.10558500    0.00008400
 H                 -0.73266400    0.49835700   -0.92961000
 S                 -3.27269600   -0.07209500   -0.00000200
 Br                 1.76434400    0.00508400   -0.00000100
 C                 -3.35630264    1.70594041    0.00000063
 H                 -2.89997221    2.08445707    0.89072375
 H                 -2.83906002    2.08732385   -0.85551486
 H                 -4.38013363    2.01485891   -0.03520544

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-311+g*
****
Br     0
S   2   1.00
      1.1590000             -3.0378769
      0.7107000              3.3703735
S   1   1.00
      0.1905000              1.0000000
P   2   1.00
      2.6910000             -0.1189800
      0.4446000              1.0424471
P   1   1.00
      0.1377000              1.0000000
P   1   1.00
      0.0376                 1.0
D   1   1.00
      0.4340                 1.0
****

BR     0
BR-ECP     3     28
f potential
  4
1    213.6143969            -28.0000000
2     41.0585380           -134.9268852
2      8.7086530            -41.9271913
2      2.6074661             -5.9336420
s-f potential
  4
0     54.1980682              3.0000000
1     32.9053558             27.3430642
2     13.6744890            118.8028847
2      3.0341152             43.4354876
p-f potential
  5
0     54.2563340              5.0000000
1     26.0095593             25.0504252
2     28.2012995             92.6157463
2      9.4341061             95.8249016
2      2.5321764             26.2684983
d-f potential
  5
0     87.6328721              3.0000000
1     61.7373377             22.5533557
2     32.4385104            178.1241988
2      8.7537199             76.9924162
2      1.6633189              9.4818270



