%mem=16000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3
scf=(maxcyc=1000,conver=8,nosym)

ch3sch3-cn-ts_6311+Gd

-1 1
 C                  0.40974400   -0.15085000   -0.29019300
 H                  0.72642000   -1.17941400   -0.32056600
 H                  0.42529000    0.38483100    0.64302100
 H                  0.19555400    0.36776700   -1.20704200
 S                 -1.83436500   -0.71441100    0.01197100
 C                 -2.36010400    1.03827500    0.18283200
 H                 -1.88872300    1.51185800    1.05037900
 H                 -2.09427700    1.61971300   -0.70619300
 H                 -3.44382900    1.10170500    0.31355200
 C                  2.48417077    0.37009886   -0.56950969
 N                  3.57595769    0.71154724   -0.76190076

