%mem=40000MB
%nprocshared=20
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3 nosymm

ch3ph2-oTs-ts_6311+Gd_ch2cl2

-1 1
 C	 0.130786000	 0.042109000	 0.358315000
 H	 0.223551000	 0.389084000	-0.657668000
 H	 0.265841000	 0.765285000	 1.144806000
 H	-0.520949000	-0.793316000	 0.553722000
 H	-2.853540000	 0.643207000	 1.336662000
 H	-2.875263000	 0.236177000	-0.700682000
 P	-2.448850000	 1.313182000	 0.138986000
 C	 6.270732000	-3.013931000	 1.115008000
 C	 6.088435000	-2.028761000	 0.134368000
 C	 4.819093000	-1.698132000	-0.327458000
 C	 3.714587000	-2.366829000	 0.200497000
 C	 3.861469000	-3.345190000	 1.182153000
 C	 5.140715000	-3.662050000	 1.629857000
 H	 6.951794000	-1.513876000	-0.274668000
 H	 4.693457000	-0.937056000	-1.088327000
 H	 2.996291000	-3.855952000	 1.587215000
 H	 5.260845000	-4.426019000	 2.391114000
 C	 7.652949000	-3.386083000	 1.578955000
 H	 8.092785000	-4.132361000	 0.908257000
 H	 8.319991000	-2.520976000	 1.581897000
 H	 7.637431000	-3.816819000	 2.582280000
 S	 2.076460000	-1.919448000	-0.352536000
 O	 1.716716000	-0.727092000	 0.586972000
 O	 1.165839000	-3.059559000	-0.112154000
 O	 2.156765000	-1.461023000	-1.756855000




