%mem=3000MB
%nprocshared=4
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3 nosymm

ch3nhcho-Ts-ts_6311+Gd_ch2cl2

-1 1
 C	 1.063077000	-0.463518000	-0.067546000
 H	 0.943275000	-1.189919000	-0.852528000
 H	 0.911993000	 0.576444000	-0.295949000
 H	 0.994139000	-0.781099000	 0.957462000
 N	-1.193607000	-0.526611000	-0.028823000
 H	-1.730951000	-0.896875000	-0.809406000
 C	-1.871358000	 0.387413000	 0.620454000
 O	-1.438730000	 1.065934000	 1.608006000
 H	-2.911830000	 0.588289000	 0.293501000
 C	 3.590783000	-4.096883000	-2.742332000
 C	 3.959468000	-3.038741000	-1.919130000
 C	 3.319934000	-2.884953000	-0.688699000
 C	 2.320544000	-3.766085000	-0.280611000
 C	 1.965180000	-4.819457000	-1.119577000
 C	 2.592307000	-5.003126000	-2.357544000
 H	 4.087677000	-4.222595000	-3.699053000
 H	 4.734626000	-2.348180000	-2.229503000
 H	 1.826109000	-3.636150000	 0.674280000
 H	 1.187753000	-5.507679000	-0.804210000
 C	 2.228098000	-6.161262000	-3.246861000
 H	 1.237591000	-6.554320000	-3.009065000
 H	 2.244463000	-5.874596000	-4.301139000
 H	 2.946173000	-6.979294000	-3.123684000
 S	 3.736483000	-1.484954000	 0.346347000
 O	 3.366707000	-1.829029000	 1.735545000
 O	 2.864867000	-0.308890000	-0.173837000
 O	 5.152003000	-1.135695000	 0.113924000




