%mem=3000MB
%nprocshared=4
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3 nosymm

ch3sh-Ts-ts_6311+Gd_ch2cl2

-1 1
 C	-2.866213000	 0.503123000	-1.127670000
 C	-1.506988000	 0.442465000	-1.414879000
 C	-0.613638000	 1.148915000	-0.609330000
 C	-1.060684000	 1.902034000	 0.474487000
 C	-2.425619000	 1.949578000	 0.746304000
 C	-3.347273000	 1.255805000	-0.046926000
 H	-3.565265000	-0.042777000	-1.753238000
 H	-1.150253000	-0.142908000	-2.254086000
 H	-0.358804000	 2.442050000	 1.098085000
 H	-2.777140000	 2.535008000	 1.589706000
 C	-4.823994000	 1.337051000	 0.231560000
 H	-5.022433000	 1.607696000	 1.270665000
 H	-5.291538000	 2.098696000	-0.402001000
 H	-5.323138000	 0.388939000	 0.017738000
 S	 1.143435000	 1.012386000	-0.923374000
 O	 1.798504000	 2.200412000	-0.335201000
 O	 1.345384000	 0.809179000	-2.372286000
 O	 1.595779000	-0.279707000	-0.190059000
 C	 1.354808000	-0.363136000	 1.624058000
 H	 1.800205000	 0.580426000	 1.887548000
 H	 0.282207000	-0.452479000	 1.620109000
 H	 1.943273000	-1.258790000	 1.716664000
 S	 1.033452000	-0.604092000	 4.266141000
 H	 2.367633000	-0.522993000	 4.486273000




