%mem=3000MB
%nprocshared=4
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3f-OTf-ts_6311+Gd-op_ch2cl2

-1 1
 S                  1.12526200    0.94981300   -0.94303100
 O                  1.78476300    2.11434900   -0.32019100
 O                  1.29435400    0.78677700   -2.39779500
 O                  1.54144600   -0.36145300   -0.24049500
 C                  1.51067900   -0.42431600    1.62869500
 H                  2.00941700    0.51771200    1.77044800
 H                  0.43901600   -0.48182900    1.69245500
 H                  2.08783300   -1.33075000    1.60778900
 F                  1.51197300   -0.59255200    3.62838900
 C                 -0.61794028    1.10514978   -0.61819826
 F                 -0.82272191    1.17730246    0.71422752
 F                 -1.08729820    2.22567491   -1.20694826
 F                 -1.26589180    0.03028346   -1.11551228

