%mem=20000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3hcooo-OTf-ts_6311+Gd_ch2cl2

-1 1
 C                 -1.34500100    0.37622400   -0.86468600
 H                 -2.07356000   -0.30606500   -0.46486900
 H                 -0.90975100    1.11473500   -0.21476900
 H                 -0.83318000    0.12340300   -1.77861800
 O                  0.06702300   -0.96563400   -0.00182600
 O                 -0.13901000   -0.87749400    1.42993600
 C                 -1.21304000   -1.49613800    1.89431400
 H                 -1.22756400   -1.35849000    2.98907000
 O                 -2.05955900   -2.11156100    1.28186100
 C                 -4.49783900   -0.12065200   -2.00579900
 S                 -3.41813000    1.11923100   -2.73415200
 O                 -2.62943900    0.44915500   -3.78443900
 O                 -2.50273200    1.57669000   -1.56550000
 O                 -4.25232800    2.26102800   -3.14387500
 F                 -5.64949178    0.46207142   -1.61003483
 F                 -3.88657641   -0.67925190   -0.93957942
 F                 -4.76803410   -1.07561052   -2.92097595

