%mem=3000MB
%nprocshared=4
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3nch33-OTf-ts_6311+Gd_ch2cl2

0 1
 C                  0.12986600   -0.08258700    0.14538700
 H                  0.26684000   -0.04955800   -0.92153700
 H                  0.07840900    0.83957700    0.69856500
 H                 -0.18273600   -1.00292100    0.60816700
 N                 -1.98845300    0.23646500   -0.25198200
 C                 -2.43980900   -0.87290400   -1.09351500
 H                 -1.87065300   -0.88305400   -2.02541700
 H                 -2.27365800   -1.81907000   -0.57441600
 H                 -3.50865200   -0.78979300   -1.33671400
 C                 -2.10902600    1.52498800   -0.93597800
 H                 -1.70628900    2.31712500   -0.30152000
 H                 -1.53894100    1.50213400   -1.86703300
 H                 -3.15588700    1.76350100   -1.17180500
 C                 -2.66299100    0.24439000    1.04766400
 H                 -2.49857900   -0.70907300    1.55345200
 H                 -2.25281800    1.04208200    1.67021500
 H                 -3.74552900    0.40341800    0.94183600
 S                  2.41700600   -0.44282300    1.86214400
 O                  1.87349500   -1.64845700    2.51822800
 O                  1.93304200   -0.35226600    0.38864100
 O                  2.18609900    0.83461500    2.56553700
 C                  4.17227412   -0.66142952    1.66303341
 F                  4.75422396   -0.75880602    2.87726246
 F                  4.40834337   -1.78895782    0.95915043
 F                  4.68549712    0.39767823    1.00167652

