%mem=3000MB
%nprocshared=4
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3nhcho-OTf-ts_6311+Gd_ch2cl2

-1 1
 C                  1.04472300   -0.44973300   -0.04890200
 H                  0.89521300   -1.22222600   -0.78307200
 H                  0.89781100    0.57548000   -0.33742000
 H                  0.99970000   -0.70114800    0.99533000
 N                 -1.19551700   -0.49900400    0.05158100
 H                 -1.74858500   -0.92852000   -0.68787700
 C                 -1.87310900    0.46226900    0.65588500
 O                 -1.44809100    1.21647400    1.56173400
 H                 -2.93129100    0.60577600    0.32443600
 S                  3.71390000   -1.48337300    0.34106200
 O                  3.31240500   -1.83013500    1.71620400
 O                  2.83910900   -0.32697300   -0.21488400
 O                  5.12833800   -1.14399200    0.11558300
 C                  3.31873159   -2.88051333   -0.68861796
 F                  4.04550365   -3.94844293   -0.29640787
 F                  2.00388462   -3.16504730   -0.57584448
 F                  3.60710027   -2.58767821   -1.97453828

