%mem=3000MB
%nprocshared=4
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3och3-OTf-ts_6311+Gd_ch2cl2

-1 1
 S                  1.13636400    0.92298900   -0.83438300
 O                  1.78424000    2.10102800   -0.23443100
 O                  1.35251200    0.68102000   -2.26804500
 O                  1.54419300   -0.37763400   -0.06763200
 C                  1.42418000   -0.39583700    1.65208700
 H                  1.95331400    0.51057600    1.89463500
 H                  0.35374200   -0.40651500    1.76781500
 H                  1.94569200   -1.33034300    1.76918500
 O                  1.28078900   -0.54360200    3.86581400
 C                  2.56534700   -0.53034600    4.33993800
 H                  2.62976100   -0.62167500    5.44823400
 H                  3.20655800   -1.36062100    3.94761800
 H                  3.13364000    0.40347600    4.09707200
 C                 -0.61507554    1.07879021   -0.55764210
 F                 -1.24443523   -0.01885109   -1.02837550
 F                 -0.85245769    1.20082772    0.76570841
 F                 -1.07667212    2.17255776   -1.20037155

