%mem=3000MB
%nprocshared=4
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3ooh-OTf-ts_6311+Gd-1_ch2cl2

-1 1
 C                  0.18916900    0.45681700    0.32939200
 H                 -0.09335300   -0.26236600    1.07737000
 H                  0.26801800    0.11154700   -0.68648200
 H                 -0.09368900    1.48457100    0.49661900
 O                 -1.96967500    0.27653400   -0.16371200
 O                 -2.05837400   -1.12684900   -0.62455000
 H                 -2.37042400   -1.58952000    0.16611400
 S                  2.79441900    1.50934900    0.06387700
 O                  1.84825400    0.49263200    0.78507700
 O                  2.69802500    1.35583100   -1.39857500
 O                  2.60284300    2.87090100    0.59390900
 C                  4.39187923    0.92680958    0.59034509
 F                  4.47029974    0.98375421    1.93686190
 F                  4.56222688   -0.34901441    0.18321512
 F                  5.35466747    1.70387548    0.05024565

