%mem=3000MB
%nprocshared=4
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3OTf-nh2-ts_6311+Gd_ch2cl2

-1 1
 C                 -0.24955000   -0.33503200    0.06200900
 H                 -0.29130400    0.00104800    1.08328200
 H                 -0.13106400    0.41641200   -0.69970900
 H                  0.21730200   -1.29106200   -0.10810500
 N                  2.11662100    0.22730700    0.45840900
 H                  2.52396100   -0.02000300   -0.45009800
 H                  2.08700400    1.25269700    0.43904600
 S                 -2.41622100   -1.26340400   -1.45978100
 O                 -1.91022100   -0.70734200   -0.08342000
 O                 -1.98021900   -0.38051300   -2.55641500
 O                 -2.09172000   -2.69324900   -1.59844800
 C                 -4.17902800   -1.10568971   -1.26994509
 F                 -4.58568025   -1.84260750   -0.21444231
 F                 -4.49512778    0.19028051   -1.06247913
 F                 -4.79323578   -1.54512735   -2.38893721

