%mem=3000MB
%nprocshared=4
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3sch3-OTf-ts_6311+Gd_ch2cl2

-1 1
 S                  1.18428000    1.13574900   -0.81316200
 O                  1.74635400    2.14605300    0.10154100
 O                  1.35462200    1.36562900   -2.25744400
 O                  1.72931900   -0.28068700   -0.47611400
 C                  1.59097800   -0.84598500    1.24117300
 H                  2.02778100    0.00788200    1.72918600
 H                  0.52403000   -0.98076800    1.26455300
 H                  2.20899200   -1.71248700    1.07953100
 C                  0.19701200   -0.21724200    4.06292300
 H                  0.69637800    0.72968200    3.83095600
 H                 -0.71041500   -0.27438100    3.45311600
 S                  1.30999900   -1.65865000    3.76079100
 H                 -0.11204400   -0.17715300    5.11204700
 C                 -0.56050109    1.03486013   -0.47558183
 F                 -0.75021999    0.73414609    0.82675369
 F                 -1.14182126    2.22133862   -0.75277429
 F                 -1.11275052    0.07257883   -1.24469514

