%mem=40000MB
%nprocshared=24
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3ash2-OTf-ts_6311+Gd_ch2cl2

-1 1
 C                  0.11472500    0.00435100    0.40303500
 H                  0.30994000    0.40529900   -0.57766200
 H                  0.23814300    0.65888500    1.24927000
 H                 -0.58765400   -0.80810400    0.49208000
 H                 -3.01117200    0.76360800    1.27670500
 H                 -2.90964800    0.46183200   -0.90608800
 S                  2.04184200   -2.00715500   -0.30938000
 O                  1.66137800   -0.87592600    0.69196600
 O                  1.19179800   -3.19618500   -0.11015100
 O                  2.11229800   -1.48132400   -1.68617700
 As                -2.38257400    1.51437100    0.08715500
 C                  3.69274593   -2.41452500    0.21689549
 F                  4.18380325   -3.39996279   -0.56430555
 F                  3.66610840   -2.82949408    1.50125958
 F                  4.48041570   -1.32307834    0.11287379

