%mem=120000MB
%nprocshared=28
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3OTf-OTf-ts_6311+Gd_ch2cl2

-1 1
 C                  1.42183200    0.60335800    0.72096000
 H                  0.71225900    0.05253600    0.13195800
 H                  1.63144100    1.62964700    0.47567100
 H                  1.93562900    0.13360800    1.54097300
 S                  3.35736600   -1.36842100   -0.47944700
 O                  3.81373100   -1.68803300    0.89020200
 O                  2.85302100    0.07806600   -0.57138900
 O                  4.31776300   -1.63421000   -1.56921800
 S                 -0.81036200    0.19125500    2.69479700
 O                 -1.62654600    0.83374800    3.74585100
 O                 -0.01060000    1.24704100    1.92737800
 O                  0.05020400   -0.92321100    3.14991100
 C                 -1.92801790   -0.49766108    1.49286525
 F                 -2.72207361    0.47904597    1.00499348
 F                 -1.22013942   -1.04820718    0.48375323
 F                 -2.68950069   -1.44631430    2.07827196
 C                  1.91546492   -2.36672832   -0.78391992
 C                  1.67506122   -3.50062285   -0.00693485
 C                  1.02577471   -2.01567709   -1.79917919
 C                  0.54558231   -4.28310942   -0.24612911
 H                  2.37636980   -3.77723489    0.79365779
 C                 -0.10452150   -2.79795684   -2.03767184
 H                  1.21496697   -1.12209848   -2.41171310
 C                 -0.34452714   -3.93164648   -1.26133864
 H                  0.35567812   -5.17651681    0.36624448
 H                 -0.80586923   -2.52090371   -2.83797300
 C                 -1.59191045   -4.79548431   -1.52481364
 H                 -1.30448688   -5.82340392   -1.60010617
 H                 -2.28469336   -4.67702556   -0.71801789
 H                 -2.05323917   -4.48622218   -2.43938061

