%mem=23000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3c6h5-OTf-ts_6311+Gd_ch2cl2

-1 1
 C                  3.28923600    0.55429400   -0.36392100
 H                  2.95571800    1.50057300   -0.75630400
 H                  3.19793500    0.40975800    0.69875100
 H                  3.14986900   -0.30574100   -0.99793900
 C                  0.79948800   -0.00795200    0.07362100
 C                  0.83317800   -1.09455800    0.97425700
 C                 -0.50465300    0.41595200   -0.26745100
 C                 -0.31245500   -1.71196900    1.49662200
 H                  1.80012700   -1.49184300    1.29695000
 C                 -1.67177200   -0.17801400    0.23807300
 H                 -0.63730200    1.25136700   -0.96006500
 C                 -1.57948500   -1.25168200    1.12748400
 H                 -0.22134300   -2.54847000    2.18886000
 H                 -2.65161500    0.19337400   -0.06024900
 H                 -2.47643300   -1.71992900    1.52490200
 S                  5.95653200   -0.34837200   -0.36277000
 O                  7.32212300    0.19571500   -0.33646400
 O                  4.97038600    0.86138200   -0.50440300
 O                  5.65423800   -1.38455800   -1.36322400
 C                  5.58934808   -1.03024506    1.23992307
 F                  6.40328392   -2.08031506    1.47942557
 F                  5.78248626   -0.08632486    2.18555106
 F                  4.30379199   -1.44124593    1.27031775

