%mem=3000MB
%nprocshared=4
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3cf3-OTf-ts_6311+Gd_ch2cl2

-1 1
 C                 -0.86877400    0.11108600    0.09812200
 H                 -0.95333300    0.13644000   -0.97492300
 H                 -0.43823700   -0.76980000    0.54578000
 H                 -0.76173900    1.04919300    0.61708000
 F                  1.74147900    1.64406900   -1.27015900
 F                  2.13780000   -0.50810700   -1.12138000
 F                  2.34643000    0.77050500    0.64765900
 C                  1.46292400    0.53275300   -0.43359500
 S                 -3.06237500   -0.33882700    1.83576200
 O                 -2.73511600    0.87164100    2.61063300
 O                 -2.56746900   -0.19516100    0.35996500
 O                 -2.62374900   -1.62294800    2.41114400
 C                 -4.82646040   -0.40327609    1.60718154
 F                 -5.14132366   -1.46240869    0.83155324
 F                 -5.43145991   -0.52884116    2.80747693
 F                 -5.24452700    0.73254171    1.00915293

