%mem=3000MB
%nprocshared=4
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3cl-OTf-ts_6311+Gd_ch2cl2

-1 1
 S                  1.12397300    0.94970300   -0.99674500
 O                  1.78812400    2.10766600   -0.36096600
 O                  1.27703400    0.82621300   -2.45975600
 O                  1.53522800   -0.36572700   -0.31990700
 C                  1.50779000   -0.42405400    1.65984300
 H                  1.99083700    0.53236000    1.74949500
 H                  0.43555400   -0.49633500    1.67814600
 H                  2.10124500   -1.31869000    1.60614200
 Cl                 1.50070500   -0.59663400    4.05030800
 C                 -0.61612399    1.10817954   -0.65711629
 F                 -1.27312279    0.04574460   -1.16905826
 F                 -0.81140850    1.15751495    0.67777321
 F                 -1.08357662    2.24147186   -1.22248039

