%mem=3000MB
%nprocshared=4
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3sch2ch3-OTf-ts_6311+Gd_ch2cl2

-1 1
 S                  3.45190100   -0.71917500   -1.80810400
 O                  2.21977700   -1.40100800   -2.24972200
 O                  4.62178700   -1.58518400   -1.56691700
 O                  3.16804300    0.19100400   -0.57951400
 C                  2.47596100   -0.58859400    0.90285100
 H                  2.42752200    0.34338900    1.43632500
 H                  1.57519100   -0.98721600    0.46935900
 H                  3.28149900   -1.26616200    1.13060700
 C                 -0.26394700   -0.71733300    2.64944600
 H                 -0.06963800    0.29540500    2.27593400
 H                 -0.68943700   -1.28077300    1.81092300
 C                 -1.28963100   -0.64708400    3.77900100
 H                 -0.91011600   -0.05846500    4.62038900
 H                 -2.22391100   -0.18244800    3.43582400
 H                 -1.53110400   -1.64586300    4.15654400
 S                  1.34186500   -1.48968100    3.14482900
 C                  3.89915985    0.47775096   -3.04734884
 F                  4.98406151    1.16772723   -2.63574084
 F                  4.18201987   -0.15703624   -4.20473184
 F                  2.87061116    1.33034246   -3.24145014

