%mem=23000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3sh-OTf-ts_6311+Gd_ch2cl2

-1 1
 S                  1.13478300    0.97815100   -0.89323400
 O                  1.78178900    2.14258500   -0.25888700
 O                  1.33680100    0.80756100   -2.34265200
 O                  1.53684000   -0.33555700   -0.17712600
 C                  1.39331900   -0.39113900    1.67606700
 H                  1.86950200    0.55173300    1.87965900
 H                  0.32018400   -0.45889700    1.71351600
 H                  1.97068100   -1.29655400    1.73177100
 S                  1.20895300   -0.58432100    4.29725400
 H                  2.53975900   -0.39151000    4.46617700
 C                 -0.61477838    1.13101611   -0.60329049
 F                 -0.84600361    1.20576486    0.72465812
 F                 -1.07440268    2.24936308   -1.20374496
 F                 -1.25084283    0.05385732   -1.11088378

