%mem=3000MB
%nprocshared=4
#p opt=(calcfc,ts,noeigentest) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=water) empiricaldispersion=gd3

ch3c6h5-nch33-ts_6311+Gd

0 1 
 C                 -1.08319500    0.32438000    0.09236100
 H                 -0.84477000   -0.19573800    1.00453100
 H                 -1.06948200    1.40107800    0.13260400
 H                 -0.74294500   -0.12858600   -0.82322300
 C                  1.58153800    0.43601600    0.18945800
 C                  1.94372700   -0.92658400    0.14800100
 C                  2.66432300    1.33245000    0.05351600
 C                  3.26385700   -1.37370400   -0.00782800
 H                  1.16716300   -1.69082500    0.23800800
 C                  3.99561500    0.91629800   -0.10710700
 H                  2.48315000    2.40960400    0.07089000
 C                  4.30147800   -0.44640600   -0.13788500
 H                  3.48532400   -2.43943100   -0.03056500
 H                  4.79231000    1.65134200   -0.20885800
 H                  5.32811300   -0.77962700   -0.26168000
 N                 -3.14913689   -0.03001734   -0.03525806
 C                 -3.81586624    0.52594190    1.15103082
 H                 -3.42591693    0.05873328    2.03111925
 H                 -3.63871167    1.58010534    1.19852496
 H                 -4.86827633    0.34366470    1.08693705
 C                 -3.68486176    0.61184811   -1.24435178
 H                 -3.50770751    1.66601157   -1.19685700
 H                 -3.19955524    0.20717008   -2.10784079
 H                 -4.73727179    0.42957064   -1.30844578
 C                 -3.39251643   -1.47826076   -0.10050682
 H                 -2.90721043   -1.88293821   -0.96399639
 H                 -3.00256624   -1.94546821    0.77958184
 H                 -4.44492639   -1.66053898   -0.16459987

