%mem=16000MB
%nprocshared=20 
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3hcooo-oTs-ts_6311+Gd

-1 1
 C                 -0.91313300    0.43504600   -0.28566500
 H                 -0.57723100   -0.58312100   -0.36658000
 H                 -1.03396700    0.88839600    0.68147600
 H                 -1.21737700    0.96988700   -1.17002600
 O                  0.82843700    1.13646500   -0.49111100
 O                  1.58661100    0.68190000    0.65399400
 C                  2.22652400   -0.47463000    0.46438800
 H                  2.76761500   -0.71786200    1.38891500
 O                  2.23111300   -1.15225300   -0.54001000
 C                 -4.84704449   -0.97720245   -1.17170892
 C                 -5.13693573   -2.34157001   -1.21270635
 C                 -5.88378484   -0.04501393   -1.13010348
 C                 -6.46328857   -2.77285862   -1.21279219
 H                 -4.31955453   -3.07650218   -1.24525156
 C                 -7.21047819   -0.47663160   -1.12919999
 H                 -5.65564222    1.03033780   -1.09779493
 C                 -7.50022059   -1.84040413   -1.17069657
 H                 -6.69203884   -3.84798439   -1.24472450
 H                 -8.02762210    0.25843015   -1.09619875
 S                 -3.15438261   -0.42648011   -1.17250733
 C                 -8.96463870   -2.31693257   -1.17017221
 H                 -9.56954050   -1.61007000   -0.64164680
 H                 -9.31277140   -2.40083744   -2.17846959
 H                 -9.02908905   -3.27098460   -0.69003590
 O                 -2.47757072   -1.21470630   -1.77302805
 O                 -2.72823666   -0.33389366    0.05216707
 O                 -3.08344010    0.64755505   -1.70299355

