%mem=16000MB
%nprocshared=24
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3hcooo-sch2h3-ts_6311+Gd

-1 1
 C                 -1.23031400    0.72304300   -0.21833600
 H                 -1.21172100   -0.34760600   -0.11587600
 H                 -1.06995300    1.34261100    0.64633300
 H                 -1.57599900    1.17055400   -1.13396200
 O                  0.55872700    0.83795000   -0.82041200
 O                  1.39185000    0.33758600    0.25307100
 C                  1.59734700   -0.98143800    0.21970400
 H                  2.23384900   -1.24673100    1.07464700
 O                  1.17377200   -1.76803400   -0.59913100
 S                 -3.63742300    0.51645300    0.47874500
 C                 -3.86333100   -1.12542800   -0.33955700
 H                 -3.06985300   -1.80029100    0.00164000
 H                 -4.80719900   -1.55622800    0.00904800
 C                 -3.85818900   -1.06403300   -1.86503600
 H                 -3.99900600   -2.06216200   -2.29915300
 H                 -4.66120400   -0.41930800   -2.23513100
 H                 -2.91190000   -0.66711000   -2.24335800

