%mem=20000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=water) empiricaldispersion=gd3

ch3c6h5-Ts-ts_6311+Gd

-1 1
 C                  2.41232900    0.03328800   -0.03538000
 H                  2.37470900    0.85737000   -0.72640100
 H                  2.22537600    0.22747400    1.00601800
 H                  2.26709200   -0.96572000   -0.40793700
 C                  0.05309700    0.08564100   -0.13697800
 C                 -0.63304200   -1.14305600   -0.07616000
 C                 -0.77134100    1.22735200   -0.07530800
 C                 -2.02762100   -1.24234900    0.03727800
 H                 -0.06579600   -2.07765100   -0.11421100
 C                 -2.16832500    1.16179600    0.03865700
 H                 -0.32038700    2.22267900   -0.11325700
 C                 -2.80425000   -0.08159600    0.09516100
 H                 -2.50980200   -2.21745700    0.08155200
 H                 -2.76098600    2.07391500    0.08418700
 H                 -3.88506800   -0.14482100    0.18519500
 C                  5.94458259   -3.19373472    3.13662476
 C                  5.74347918   -2.73193744    1.83507431
 C                  5.87921208   -1.37397137    1.56376251
 C                  6.20674116   -0.47601484    2.58241233
 C                  6.40285115   -0.95109818    3.87395487
 C                  6.27399403   -2.31581659    4.17370968
 H                  5.84491897   -4.25463695    3.34340421
 H                  5.49297489   -3.42584613    1.04198721
 H                  6.31647985    0.58150333    2.37030541
 H                  6.66343757   -0.25298923    4.66371812
 C                  6.47976497   -2.80773082    5.58211617
 H                  7.42048531   -2.43520109    5.99743214
 H                  5.67841670   -2.45360760    6.23889643
 H                  6.49322358   -3.89839936    5.62931036
 S                  5.57731959   -0.74136607   -0.09767665
 O                  6.62461001    0.27701553   -0.41697452
 O                  4.22450400   -0.12152100    0.06865900
 O                  5.56747032   -1.88322933   -1.05978403

