%mem=3000MB
%nprocshared=4
#p opt=(calcfc,ts,noeigentest,maxstep=5) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3nch33-Ts-ts_6311+Gd

0 1
 C                 -0.05391900    0.01320600    0.08965400
 H                  0.12499700   -0.14862800   -0.95930300
 H                  0.00166100    1.00565700    0.50221200
 H                 -0.25777000   -0.82454400    0.73396200
 N                 -2.00401700    0.25517300   -0.26304200
 C                 -2.49664200   -0.98497200   -0.87583900
 H                 -1.95497800   -1.17338000   -1.80408900
 H                 -2.32900900   -1.82019900   -0.19400100
 H                 -3.56825800   -0.91760400   -1.09773900
 C                 -2.14479300    1.39883600   -1.17327000
 H                 -1.71952900    2.28957400   -0.70811400
 H                 -1.60765800    1.19455200   -2.10088100
 H                 -3.19862100    1.58967800   -1.40791000
 C                 -2.65255100    0.51234800    1.02890700
 H                 -2.48119100   -0.33258700    1.69760600
 H                 -2.22536900    1.40986700    1.47893500
 H                 -3.73270800    0.65583600    0.90734800
 C                  6.44992587    0.17053595    1.88289982
 C                  5.07233167    0.31175943    2.05617150
 C                  4.22542347   -0.72005027    1.66346223
 C                  4.74354141   -1.88566959    1.09413448
 C                  6.11781295   -2.01101618    0.92706734
 C                  6.99371734   -0.98627667    1.31644359
 H                  7.10827805    0.97439316    2.19689041
 H                  4.66732874    1.21268881    2.50063486
 H                  4.08404899   -2.69131558    0.79184179
 H                  6.51984354   -2.92006965    0.49005409
 C                  8.47855237   -1.13808925    1.11607389
 H                  8.83645666   -2.08993300    1.51871330
 H                  8.73047558   -1.12727393    0.05055038
 H                  9.03412528   -0.33188340    1.59912374
 S                  2.43828105   -0.54609099    1.82950077
 O                  1.96269128   -1.85547699    2.37281661
 O                  1.87485200   -0.26460500    0.47108300
 O                  2.22831246    0.58601472    2.78021059

