%mem=40000MB
%nprocshared=20
#p opt=(calcfc,ts,noeigentest,maxstep=5) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3Ts-Ts-ts_6311+Gd

-1 1
 C                  0.40704900   -0.14734700    0.01858900
 H                  0.40980500   -0.23135100   -1.05290100
 H                  0.76280700    0.74768400    0.49374100
 H                 -0.01735300   -0.93391700    0.61309400
 C                  3.75225312   -4.34024343   -2.84209395
 C                  3.91160105   -3.21190951   -2.03636218
 C                  3.30916512   -3.17760232   -0.78256821
 C                  2.54514839   -4.25695642   -0.33254393
 C                  2.39478622   -5.37329623   -1.14705119
 C                  2.99340633   -5.43398321   -2.41468067
 H                  4.22945087   -4.36666354   -3.81666483
 H                  4.50633986   -2.37461879   -2.38056970
 H                  2.07906860   -4.23196930    0.64598654
 H                  1.80575450   -6.21420721   -0.79364245
 C                  2.80836798   -6.64853291   -3.28563414
 H                  3.03447306   -7.56692968   -2.73641253
 H                  1.77108892   -6.72798971   -3.62719144
 H                  3.44920633   -6.61161591   -4.16877040
 S                  3.45647104   -1.71379929    0.26016391
 O                  3.72171804   -2.21449397    1.64393351
 O                  2.14527900   -0.99710000    0.16475400
 O                  4.58754638   -0.91022973   -0.29169102
 C                 -5.69232100   -0.86760500    1.27573400
 C                 -4.29676700   -0.87818000    1.28281300
 C                 -3.60489700    0.32885300    1.30500700
 C                 -4.29583200    1.54285100    1.31315400
 C                 -5.68584700    1.53701500    1.30480600
 C                 -6.40745000    0.33377400    1.28446800
 H                 -6.22896700   -1.81106300    1.26562600
 H                 -3.75772800   -1.81769000    1.28021800
 H                 -3.75686900    2.48329700    1.33452700
 H                 -6.22186400    2.48121600    1.31736100
 C                 -7.91318900    0.35037000    1.26434900
 H                 -8.31192100    0.99598500    2.05201300
 H                 -8.28527300    0.74182500    0.31185800
 H                 -8.32832100   -0.65030800    1.39953500
 S                 -1.80219000    0.34749300    1.26489900
 O                 -1.37507700    1.37506800    2.26366500
 O                 -1.41755700    0.72837800   -0.13115600
 O                 -1.35422300   -1.03081000    1.62435100

