%mem=20000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3Ts-nh2-ts_6311+Gd

-1 1
 C                 -0.09693200    0.01115700    0.01139300
 H                  0.00481000    1.08080300    0.00465800
 H                 -0.01306800   -0.53400100   -0.91122700
 H                 -0.02487600   -0.51245000    0.94738000
 N                  2.10977700    0.00685800    0.06591200
 H                  2.31076600   -0.98826200   -0.07177100
 H                  2.31502000    0.42205300   -0.84797700
 C                 -6.27619100   -2.13482300   -1.00262700
 C                 -4.88063700   -2.14539800   -0.99554800
 C                 -4.18876700   -0.93836500   -0.97335400
 C                 -4.87970200    0.27563300   -0.96520700
 C                 -6.26971700    0.26979700   -0.97355500
 C                 -6.99132000   -0.93344400   -0.99389300
 H                 -6.81283700   -3.07828100   -1.01273500
 H                 -4.34159800   -3.08490800   -0.99814300
 H                 -4.34073900    1.21607900   -0.94383400
 H                 -6.80573400    1.21399800   -0.96100000
 C                 -8.49705900   -0.91684800   -1.01401200
 H                 -8.89579100   -0.27123300   -0.22634800
 H                 -8.86914300   -0.52539300   -1.96650300
 H                 -8.91219100   -1.91752600   -0.87882600
 S                 -2.38606000   -0.91972500   -1.01346200
 O                 -1.95894700    0.10785000   -0.01469600
 O                 -2.00142700   -0.53884000   -2.40951700
 O                 -1.93809300   -2.29802800   -0.65401000

