%mem=3000MB
%nprocshared=4
#p opt=(calcfc,ts,noeigentest,maxstep=5) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3nhcho-sch3-ts_6311+Gd

-1 1
 C                  0.41717100   -0.08761500   -0.05034300
 H                  0.36965500   -0.10276400   -1.12434200
 H                  0.72043200    0.80971800    0.45706400
 H                 -0.01350100   -0.89520000    0.51189700
 N                 -1.52608200    0.76267600   -0.12830500
 H                 -2.01911600    0.92819500   -1.00172700
 C                 -2.12915800    1.30513400    0.89969400
 O                 -1.71275200    1.27202800    2.10153500
 H                 -3.08324200    1.83591000    0.70852200
 S                  2.25456558   -0.87617942   -0.00400377
 C                  4.03456558   -0.87617942   -0.00400377
 H                  4.39123193   -1.34978493    0.88671893
 H                  4.39123193   -1.41076493   -0.85951967
 H                  4.39123244    0.13201165   -0.03921058

