%mem=20000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=2) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm scf=qc empiricaldispersion=gd3
int=ultrafinegrid

ch3nhcho-och3-ts_6311+Gd

-1 1
 C                  0.50791300   -0.38544400    0.05396400
 H                  0.76465700   -0.17474000   -0.96896300
 H                  0.86535900    0.25475300    0.83950500
 H                 -0.15448800   -1.19945300    0.28563100
 N                 -1.08462700    0.82992600   -0.17043500
 H                 -1.41087300    1.11812000   -1.08881200
 C                 -1.76129300    1.37439800    0.81033300
 O                 -1.55401200    1.17678100    2.04845100
 H                 -2.58385400    2.06340400    0.53429900
 O                  1.99580310   -1.55606069    0.26819112
 C                  3.21889300   -0.87230500   -0.01716700
 H                  3.87003278   -0.93783014    0.82936914
 H                  3.01169370    0.15584054   -0.22902830
 H                  3.69013167   -1.32330400   -0.86536156

