%nprocshared=2
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=water)
empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3ash2_6311+Gd_aq

0 1
 As                 0.42269400    0.00000000   -0.06497400
 H                  0.62794600   -1.10487800    0.97619600
 H                  0.62794400    1.10488000    0.97619500
 C                 -1.56640100    0.00000000    0.02264600
 H                 -1.93589700   -0.88660500   -0.49631000
 H                 -1.93460300   -0.00000100    1.04850500
 H                 -1.93589500    0.88660600   -0.49630800

