%mem=40000MB
%nprocshared=20
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/genecp
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3c6h5-i-ts_6311+Gd_ch2cl2

-1 1
 C                  0.24064600   -0.31678700   -0.02413900
 H                  0.60605600   -0.65900000    0.92996200
 H                  0.04506000    0.74008400   -0.10467500
 H                  0.66701200   -0.78718600   -0.89489000
 C                  2.85823900    0.37671800    0.00937000
 C                  3.50125900   -0.86873700    0.17100300
 C                  3.74079000    1.46688600   -0.15764400
 C                  4.89425900   -1.03148100    0.17051600
 H                  2.89692600   -1.77092500    0.30350900
 C                  5.13859700    1.33784600   -0.16362900
 H                  3.33791100    2.47409900   -0.29132000
 C                  5.72416700    0.08011800    0.00142100
 H                  5.33379800   -2.01996600    0.29972900
 H                  5.77095000    2.21495700   -0.29710300
 H                  6.80543400   -0.03176200   -0.00223200
 I                 -1.81114400   -1.13715300   -0.03228400

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-311+g*
****
I     0
S   2   1.00
      0.7242000             -2.9731048
      0.4653000              3.4827643
S   1   1.00
      0.1336000              1.0000000
P   2   1.00
      1.2900000             -0.2092377
      0.3180000              1.1035347
P   1   1.00
      0.1053000              1.0000000
P   1   1.00
      0.0308                 1.0
D   1   1.00
      0.2940                 1.0
****

I     0
I-ECP     3     46
f potential
  5
0      1.0715702             -0.0747621
1     44.1936028            -30.0811224
2     12.9367609            -75.3722721
2      3.1956412            -22.0563758
2      0.8589806             -1.6979585
s-f potential
  5
0    127.9202670              2.9380036
1     78.6211465             41.2471267
2     36.5146237            287.8680095
2      9.9065681            114.3758506
2      1.9420086             37.6547714
p-f potential
  5
0     13.0035304              2.2222630
1     76.0331404             39.4090831
2     24.1961684            177.4075002
2      6.4053433             77.9889462
2      1.5851786             25.7547641
d-f potential
  5
0     40.4278108              7.0524360
1     28.9084375             33.3041635
2     15.6268936            186.9453875
2      4.1442856             71.9688361
2      0.9377235              9.3630657

