%mem=20000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3ash2-nch33-ts_6311+Gd_ch2cl2

0 1
 C                  0.23430400    0.00573000   -0.20990400
 H                  0.09708100   -0.89974400   -0.77608500
 H                  0.27296500    0.94692400   -0.73160000
 H                  0.05159100   -0.00240700    0.85101700
 H                 -2.42410400    1.33744800    0.55766000
 H                 -2.63350900   -0.72953600    0.61103800
 N                  2.17084600   -0.18576500   -0.04554400
 C                  2.65685200    0.95498500    0.74466300
 H                  3.74404700    0.90650900    0.87364000
 H                  2.40028300    1.88548900    0.23669500
 H                  2.18225200    0.94575300    1.72670700
 C                  2.42333700   -1.46358100    0.63654800
 H                  2.00163000   -2.27924400    0.04788600
 H                  3.49863200   -1.63340000    0.76330800
 H                  1.94715800   -1.45261800    1.61782700
 C                  2.72839100   -0.17912000   -1.40601600
 H                  2.29977600   -1.00278100   -1.97849500
 H                  2.47744300    0.76145900   -1.89791700
 H                  3.81845600   -0.28984600   -1.38215200
 As                -2.41002700    0.26666100   -0.39253400

