%mem=20000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3ash2-nh2-ts_6311+Gd_ch2cl2

-1 1
 C                  0.04954400    0.16064000   -0.16763700
 H                  0.11513500   -0.30878900   -1.13179000
 H                  0.22299600    1.21722200   -0.07674900
 H                 -0.06782000   -0.44537300    0.71089300
 H                 -2.53898100    0.81744600    1.00598900
 H                 -2.67533400   -0.88044900   -0.18390000
 N                  2.20018100   -0.21434800    0.03031700
 H                  2.39922000    0.29581600    0.89697800
 H                  2.56315900    0.40245500   -0.70372600
 As                -2.36752700    0.50224200   -0.37852400