%mem=20000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3ash2-sch3-ts_6311+Gd_ch2cl2

-1 1
 C                  0.26997200   -0.04990400    0.02893100
 H                  0.27703500   -0.29125200   -1.01851700
 H                  0.53398700    0.94072400    0.35179700
 H                 -0.11751500   -0.75827100    0.73822700
 H                 -2.40755700    0.83460900    1.12233300
 H                 -2.67743400   -0.52247800   -0.42709000
 S                  2.53635600   -0.81531000    0.29363000
 C                  3.16645900    0.41265200   -0.92287700
 H                  2.94606100    1.43680900   -0.60522900
 H                  4.25097400    0.32102900   -1.02871900
 H                  2.71923000    0.26073000   -1.91043900
 As                -2.17295000    0.80921900   -0.28879400

