%mem=20000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3ash2-sch2ch3-ts_6311+Gd_ch2cl2

-1 1
 C                  0.42084700   -0.00753100    0.13554300
 H                  0.54511100    0.16963000   -0.91770800
 H                  0.67877900    0.75707200    0.84343800
 H                 -0.07398100   -0.89977500    0.47316500
 H                 -2.31351700    0.66278900    1.24498500
 H                 -2.48530500   -0.05323300   -0.69763800
 S                  2.59587100   -1.05134300    0.25165300
 C                  3.40213500    0.13657900   -0.90916500
 H                  4.37314100   -0.28198400   -1.19337600
 H                  2.80639200    0.18961900   -1.82778800
 C                  3.59377300    1.54059100   -0.33981400
 H                  4.21108300    1.51747700    0.56357400
 H                  4.08599100    2.19638200   -1.07009000
 H                  2.63576600    1.99779400   -0.07616900
 As                -1.93444200    1.10419300   -0.06213600

