%mem=20000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3ash2-och2ch3-ts_6311+Gd_ch2cl2

-1 1
 C                  0.32626900   -0.01466600   -0.02680200
 H                  0.46749800   -0.69398200   -0.84685000
 H                  0.43418500    1.04411400   -0.18552900
 H                  0.05637400   -0.39450900    0.94132700
 H                 -2.44617200    0.85208100    0.58752300
 H                 -2.44835100   -1.10829600   -0.10354300
 O                  2.23403200   -0.14233900    0.53521400
 C                  3.06077500    0.37532000   -0.44538000
 H                  4.01441700    0.72772200   -0.00012300
 H                  2.62024500    1.27988100   -0.92579500
 C                  3.40787500   -0.62048100   -1.56457600
 H                  2.50513500   -0.95179100   -2.08898200
 H                  4.08536800   -0.17734300   -2.30707000
 H                  3.89389100   -1.50868100   -1.14489500
 As                -2.10069800    0.17754300   -0.62614200

