%mem=40000MB
%nprocshared=24
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3ash2-oTs-ts_6311+Gd_ch2cl2

-1 1
 C                  0.10781400   -0.00842800    0.39041500
 H                  0.28492500    0.39093200   -0.59426500
 H                  0.23904500    0.65079400    1.23117800
 H                 -0.58677000   -0.82567900    0.49293500
 H                 -2.91519400    0.77635100    1.25619700
 H                 -2.85232900    0.48357100   -0.80113500
 C                  6.28317300   -2.99477300    1.10883400
 C                  6.06649600   -2.01290900    0.13244800
 C                  4.78405900   -1.71828300   -0.32121000
 C                  3.69992800   -2.41744400    0.20705200
 C                  3.88430400   -3.39612400    1.18151100
 C                  5.17415900   -3.67812400    1.62412300
 H                  6.91254900   -1.47112200   -0.27970300
 H                  4.62784200   -0.95947200   -1.07914900
 H                  3.03320400   -3.93291600    1.58407000
 H                  5.31959100   -4.44194100    2.38207400
 C                  7.67876300   -3.32887200    1.56767200
 H                  8.12894700   -4.08502200    0.91439600
 H                  8.33013800   -2.45164300    1.54410500
 H                  7.68285300   -3.73208300    2.58317100
 S                  2.03759300   -2.00898500   -0.33295200
 O                  1.65636400   -0.87205000    0.66247000
 O                  1.18512100   -3.19550600   -0.12974100
 O                  2.11233100   -1.48991400   -1.71183900
 As                -2.33697700    1.44421300    0.12805800

