%mem=3000MB
%nprocshared=4 
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3ash2-oh-ts_6311+Gd_ch2cl2

-1 1
 C                  0.26979400    0.02804400   -0.01751700
 H                  0.34162200   -0.33612200   -1.02605800
 H                  0.45635700    1.06480700    0.19416000
 H                 -0.00375600   -0.64143900    0.77610500
 H                 -2.41968400    0.77816300    0.98511500
 H                 -2.56749700   -0.79611400   -0.36339100
 O                  2.18177700   -0.45764800    0.36815300
 H                  2.68573100    0.04620100   -0.28839600
 As                -2.14394000    0.56978600   -0.40308600

