%mem=3000MB
%nprocshared=4 
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3ash2-och3-ts_6311+Gd_ch2cl2

-1 1
 C                  0.22986200    0.00451200   -0.04018200
 H                  0.24077900   -0.15684700   -1.10420300
 H                  0.49809600    0.96894500    0.35550400
 H                 -0.05302700   -0.79143900    0.62386100
 H                 -2.36472400    0.70354900    1.22224500
 H                 -2.65491400   -0.58592600   -0.38122200
 O                  2.11298300   -0.62570300    0.10940900
 C                  2.89427600    0.21079800   -0.66096400
 H                  2.86152300    1.27654400   -0.33787300
 H                  3.96219600   -0.07988000   -0.63115000
 H                  2.61268400    0.21829500   -1.73889300
 As                -2.14698300    0.73817700   -0.19148300

