%mem=3000MB
%nprocshared=4
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3ash2-ash2-ts_6311+Gd_ch2cl2

-1 1
 C                  0.30568400    0.12622100    0.01825100
 H                  0.41117800   -0.09988700   -1.02705700
 H                  0.47094600    1.12847400    0.36956800
 H                  0.04069700   -0.64759100    0.71500200
 H                 -2.52062900    0.58153300    1.15561700
 H                 -2.56192900   -0.84327800   -0.52634000
 H                  2.68273700   -1.62351200   -0.39369900
 H                  3.15956300    0.35905600   -0.78848100
 As                -2.24813900    0.65304600   -0.35658800
 As                 2.80559200   -0.41490900    0.36070400