%mem=3000MB
%nprocshared=4  
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3ash2-sh-ts_6311+Gd_ch2cl2

-1 1
 C                  0.30001800    0.00954600    0.00260100
 H                  0.31539900   -0.34100100   -1.01319000
 H                  0.42753200    1.05678000    0.20687500
 H                 -0.06054300   -0.63999600    0.77965500
 H                 -2.50058700    0.80153100    0.97110600
 H                 -2.64334900   -0.78508400   -0.36253900
 H                  3.01377100    0.26474700   -0.56506800
 S                  2.56978400   -0.54044900    0.42842200
 As                -2.25441173    0.67238054   -0.43054570

