%mem=40000MB
%nprocshared=24
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3ash2-och2ch3-ts_6311+Gd_ch2cl2

-1 1
 C                  0.32626900   -0.01466600   -0.02680200
 H                  0.46749800   -0.69398200   -0.84685000
 H                  0.43418500    1.04411400   -0.18552900
 H                  0.05637400   -0.39450900    0.94132700
 H                 -2.44617200    0.85208100    0.58752300
 H                 -2.44835100   -1.10829600   -0.10354300
 O                  2.23403200   -0.14233900    0.53521400
 C                  3.06077500    0.37532000   -0.44538000
 H                  2.84713751    1.45325186   -0.60125158
 H                  2.87520319   -0.09743950   -1.43793096
 C                  4.56142402    0.23614964   -0.13979557
 H                  4.84638352   -0.81709331   -0.04395796
 H                  5.18016882    0.68200767   -0.93038452
 H                  4.80377427    0.73391984    0.80610830
 As                -2.10069800    0.17754300   -0.62614200

