%mem=16000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=6) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3
scf=(maxcyc=1000,conver=8,nosym)

ch3ash2-f-ts_6311+Gd_ch2cl2

-1 1
 C                 -1.11444500    0.00005100   -0.03362400
 H                 -0.96116300   -0.92171200   -0.56995600
 H                  1.86275500   -1.10284700    1.01821800
 H                 -0.92554800    0.00054800    1.02704300
 H                  1.86299400    1.10257800    1.01849900
 As                 1.86081200    0.00000100   -0.05784000
 H                 -0.96122700    0.92131400   -0.57083500
 F                 -3.27046700   -0.00001300    0.01102900

