%mem=15000MB
%nprocshared=7
#p opt(calcfc,ts,noeigentest) freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

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0 1
 C                 -1.37997800    0.28002700    0.27522000
 H                 -1.31862300    0.48326100   -0.78532100
 H                 -2.19273700    1.96314000    0.45902800
 C                 -0.28784100    0.46343400    1.10477700
 H                 -0.25063600   -0.02036400    2.07167600
 H                  0.66671300    0.68638400    0.64816300
 B                 -1.24253900    1.99371400    1.24183700
 C                 -1.79369500    2.18849800    2.73793300
 C                 -0.30123300    3.23649800    0.82655200
 H                 -2.40977300    1.34862700    3.08075500
 C                 -0.60826400    2.33034200    3.71970400
 C                 -2.71261900    3.43532200    2.68519400
 C                  0.86953800    3.35035000    1.82925800
 H                  0.12917400    3.13346200   -0.17718900
 C                 -1.22857100    4.47771800    0.80374000
 H                 -0.12832200    1.35009800    3.81912900
 H                 -0.97570400    2.58097900    4.72229700
 C                  0.46531000    3.36399100    3.31813100
 C                 -2.06940600    4.70188600    2.07988300
 H                 -3.08218700    3.67928300    3.68885000
 H                 -3.59277100    3.16794800    2.09046200
 H                  1.45860700    4.25140400    1.61887800
 H                  1.54846400    2.50684700    1.65999200
 H                 -1.90834700    4.36214200   -0.04742200
 H                 -0.64267900    5.38454400    0.60883100
 H                  1.36034100    3.19600800    3.92618400
 H                  0.12032500    4.36244200    3.58577600
 H                 -2.86183400    5.42231700    1.85245600
 H                 -1.45104500    5.18532200    2.83628200
 C                 -2.51404723   -0.66587464    0.71197745
 H                 -2.12703476   -1.65655256    0.82893305
 H                 -2.92042161   -0.32950125    1.64289785
 S                 -3.79264443   -0.67071982   -0.52639476
 C                 -5.10451703   -1.76281037   -0.02168840
 F                 -4.85648645   -3.00721768   -0.48259108
 F                 -6.27647710   -1.32146829   -0.52589743
 F                 -5.17554662   -1.78801575    1.32620607



