%mem=6000MB
%nprocshared=4
#p opt(calcfc,ts,noeigentest) freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

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0 1
 C                 -1.48615700    0.42795600    0.27712800
 H                 -1.25245400    0.27979700   -0.77629900
 H                 -2.13533870    1.98943417    0.56103890
 C                 -0.37766852    0.28777026    1.05249968
 H                 -0.48603952   -0.56778774    1.73469468
 H                  0.49812148    0.03555626    0.43884968
 S                 -2.74905100   -0.84374600    0.76080600
 C                 -4.04209300   -0.40919500   -0.44314100
 F                 -4.48574500    0.86163600   -0.31277900
 F                 -3.63541900   -0.53320500   -1.72727600
 F                 -5.09736100   -1.22621300   -0.27187100
 B                 -1.16990207    2.10036192    1.34724952
 C                 -1.75584882    2.30724015    2.79048747
 C                 -0.32210150    3.33911103    0.88468015
 H                 -2.35881364    1.45665177    3.12838261
 C                 -0.54526052    2.42977341    3.75958583
 C                 -2.68501024    3.55170392    2.75690929
 C                  0.88110080    3.45164014    1.86624693
 H                  0.09421517    3.23471347   -0.12245381
 C                 -1.25917743    4.57974509    0.86759216
 H                 -0.06035689    1.44753109    3.81351124
 H                 -0.90533325    2.64131709    4.77271057
 C                  0.51021883    3.47627880    3.35974638
 C                 -2.05335938    4.82314220    2.16315006
 H                 -3.05453325    3.76385219    3.76654520
 H                 -3.56933916    3.29081643    2.16305006
 H                  1.47042097    4.34204353    1.62001918
 H                  1.54198054    2.59555581    1.68401456
 H                 -1.96933960    4.44874504    0.04220987
 H                 -0.67653954    5.47467509    0.62188910
 H                  1.41577499    3.30813660    3.95087251
 H                  0.16363482    4.47147846    3.63515776
 H                 -2.84582298    5.55002778    1.95990126
 H                 -1.40993128    5.29441437    2.90507035


