%mem=20000MB
%nprocshared=14
#p opt(calcfc,ts,noeigentest) freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

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0 1
 Cu                 2.33173500   -0.87313400    4.42577400
 N                  3.79701400    1.15511300    5.94953900
 N                  4.78369200   -0.73493100    6.13847700
 C                  3.89904800   -2.59030800    8.16509400
 H                  4.17202300   -1.55686800    8.38910300
 C                  3.71236100   -0.14085400    5.55704100
 C                  4.90256700    1.37010200    6.75779000
 H                  5.13430500    2.33784500    7.16550900
 C                  5.52868600    0.17572000    6.87373000
 H                  6.41844700   -0.11197800    7.40489100
 C                  5.11193100   -2.12807700    5.96667400
 C                  4.70795500   -3.03808900    6.95593700
 C                  4.18586100   -3.40896900    9.42793000
 H                  3.67796300   -2.95812200   10.28352700
 H                  5.25446600   -3.44722100    9.65177300
 H                  3.81995400   -4.43438500    9.34340400
 C                  5.01498200   -4.38168000    6.74807800
 H                  4.71421400   -5.12005700    7.47860000
 C                  5.68759800   -4.79328100    5.60460800
 H                  5.90712900   -5.84428000    5.45959000
 C                  6.06902900   -3.87035100    4.64377100
 H                  6.58150400   -4.20780600    3.75195900
 C                  5.78902500   -2.51224500    4.80310500
 C                  6.18276300   -1.52108600    3.71877500
 H                  5.94001300   -0.51676000    4.06706100
 C                  5.37106800   -1.77013200    2.43916000
 H                  5.58842100   -2.75464700    2.01894200
 H                  5.60713400   -1.02008700    1.68096500
 H                  4.29808600   -1.73035800    2.63898400
 C                  7.69083300   -1.54921700    3.43524700
 H                  8.00848000   -2.51338200    3.03197400
 H                  8.26969600   -1.35957100    4.34214500
 H                  7.95220300   -0.78326700    2.70075500
 C                  2.85120000    2.15806600    5.53132700
 C                  3.10114800    2.85024700    4.33767400
 C                  2.14339300    3.77421300    3.91965500
 H                  2.29195600    4.31757100    2.99536100
 C                  0.99010700    3.99139900    4.66088100
 H                  0.25007100    4.69991000    4.31039600
 C                  0.76844800    3.28682000    5.83480600
 H                 -0.14658800    3.45093400    6.38907000
 C                  1.69392600    2.35018300    6.29753800
 C                  1.40212300    1.53990700    7.55051600
 H                  2.28936600    0.95391400    7.79347500
 C                  1.10466700    2.43779500    8.75897500
 H                  1.91801900    3.14380900    8.94324600
 H                  0.97501700    1.82912000    9.65702600
 H                  0.18698900    3.01293800    8.61812400
 C                  0.25510400    0.55159300    7.29412600
 H                 -0.66814500    1.07734600    7.03983800
 H                  0.06312600   -0.05226900    8.18384600
 H                  0.48334500   -0.13225800    6.47645200
 C                  4.32752000    2.57288200    3.48161900
 H                  5.00767600    1.94032800    4.05319500
 C                  5.09274400    3.85396700    3.12639000
 H                  4.50162500    4.51799500    2.49206300
 H                  6.00680100    3.60791400    2.58045100
 H                  5.37404400    4.41076300    4.02310800
 C                  3.93299000    1.79238800    2.21863200
 H                  3.43840100    0.85358300    2.47534700
 H                  4.81581300    1.55765800    1.61946300
 H                  3.24687400    2.37203200    1.59644800
 C                  2.39828000   -2.61060900    7.83098500
 H                  2.16807400   -1.97297400    6.97909000
 H                  1.80995900   -2.26117800    8.68281100
 H                  2.06861900   -3.62042300    7.57858900
 C                  0.81269200   -1.05578100    3.07132400
 H                  1.58379900   -0.80267600    2.32249200
 C                  0.83792700   -2.57545200    4.49336100
 O                  1.59065000   -3.45444000    4.14412700
 O                 -0.08478200   -2.33572700    5.23003000
 H                  0.25482500   -1.85801200    2.58885900
 C                 -0.10736900    0.12064100    3.38221200
 H                  0.47489700    1.01479800    3.61915600
 H                 -0.68905300   -0.12121600    4.27307300
 C                 -1.06723700    0.44450500    2.22956000
 H                 -0.51981100    0.66859600    1.31154700
 H                 -1.72594100   -0.40282300    2.02823100
 C                 -1.94976200    1.63130500    2.50676800
 F                 -1.23764400    2.77592600    2.67875400
 F                 -2.81645400    1.87102700    1.48770300
 F                 -2.70108400    1.47558300    3.62431200




