%mem=32000MB
%nprocshared=14
#p opt(calcfc,ts,noeigentest) freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

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0 1
 Cu                 2.82588000   -0.61606800    4.23745200
 N                  4.35211700    1.09551900    6.06823600
 N                  4.99855900   -0.93399400    6.30717500
 C                  3.41528900   -2.60677900    8.05032200
 H                  3.73568600   -1.58074600    8.25956900
 C                  4.11427100   -0.16636000    5.60631800
 C                  5.35745700    1.11600100    7.02675900
 H                  5.67843600    2.03009500    7.50137200
 C                  5.76835200   -0.16890800    7.17749200
 H                  6.52200900   -0.61020400    7.81083600
 C                  5.10975400   -2.36080200    6.14898000
 C                  4.35378100   -3.18926900    6.99984100
 C                  3.45617200   -3.37063200    9.38319100
 H                  2.85052900   -2.84718800   10.13242400
 H                  4.47857900   -3.45268600    9.77058700
 H                  3.04889500   -4.38396400    9.28993900
 C                  4.44248800   -4.57040500    6.79412000
 H                  3.86369500   -5.24422900    7.41758700
 C                  5.24652200   -5.09411200    5.78251100
 H                  5.29340400   -6.16959800    5.63250700
 C                  5.98465700   -4.24746900    4.95851300
 H                  6.59568000   -4.66913800    4.16636800
 C                  5.93575400   -2.85742100    5.12534500
 C                  6.71758500   -1.93649800    4.19577800
 H                  6.66099400   -0.91935900    4.59626300
 C                  6.08235900   -1.91297000    2.79358700
 H                  6.11873500   -2.90396900    2.32773600
 H                  6.61849700   -1.21100700    2.14344700
 H                  5.03228100   -1.60540300    2.84118400
 C                  8.20667200   -2.31469500    4.12439500
 H                  8.35642700   -3.30014900    3.66821200
 H                  8.66539800   -2.33327600    5.12011300
 H                  8.75196400   -1.58578100    3.51304600
 C                  3.63798900    2.24695100    5.57832300
 C                  4.15935400    2.93161400    4.46573500
 C                  3.41737200    4.00896100    3.96744200
 H                  3.78027500    4.55220100    3.10018800
 C                  2.21150600    4.38206300    4.55735700
 H                  1.64720400    5.21774100    4.15192500
 C                  1.72095400    3.68380400    5.65847600
 H                  0.77290800    3.97707500    6.09919500
 C                  2.42280500    2.59659500    6.19354800
 C                  1.84274200    1.80039000    7.35574700
 H                  2.60546700    1.09741100    7.70588300
 C                  1.46710000    2.69654500    8.54785400
 H                  2.31722500    3.30616100    8.87611900
 H                  1.14404400    2.08072700    9.39579500
 H                  0.64169200    3.37561500    8.30454500
 C                  0.63698600    0.96930200    6.88030000
 H                 -0.16929600    1.61806900    6.51739300
 H                  0.23868900    0.36155400    7.70176900
 H                  0.92078800    0.29862800    6.06271600
 C                  5.44569000    2.49225600    3.77714500
 H                  5.94629700    1.76167000    4.42067900
 C                  6.42525700    3.65877000    3.56783900
 H                  6.02499100    4.41107300    2.87838800
 H                  7.36484100    3.29031600    3.13897600
 H                  6.65781600    4.16130800    4.51421600
 C                  5.12169300    1.78398100    2.44883100
 H                  4.46190100    0.92614300    2.61474300
 H                  6.04035000    1.42502500    1.96885900
 H                  4.61810800    2.46452200    1.75178000
 C                  1.97879300   -2.53509600    7.49705200
 H                  1.94005600   -1.96485900    6.56322900
 H                  1.31232100   -2.05460900    8.22376500
 H                  1.59190600   -3.53911500    7.28954400
 C                  1.28719387    0.14327533    3.01398870
 C                  1.46162988    0.45549973    1.51075711
 C                 -0.19964768    0.30320177    3.40500167
 H                  1.83905058    0.93105732    3.56347508
 C                  0.88187065    1.82368091    1.10249334
 H                  0.95704845   -0.32275726    0.91509956
 H                  2.52404443    0.40699357    1.23205989
 C                 -0.79064314    1.66820366    3.00078945
 H                 -0.79251869   -0.49116585    2.92178899
 H                 -0.32751931    0.15630431    4.48691369
 C                 -0.59747788    1.93795475    1.50079704
 H                  0.99806199    1.99188818    0.02113087
 H                  1.45218362    2.61864388    1.60804548
 H                 -1.85808490    1.72615841    3.26254914
 H                 -0.28233730    2.45889114    3.57449067
 H                 -0.99640659    2.92611822    1.23064904
 H                 -1.17929576    1.19877646    0.92724413
 C                  1.33958855   -1.74997777    2.78228479
 O                  0.35818711   -2.11381048    2.27760982
 O                  1.90830645   -2.29926908    3.63330559




