%mem=20000MB
%nprocshared=14
#p opt(calcfc,ts,noeigentest) freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

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0 1
 Cu                 2.25176000   -0.45272800    4.60619700
 N                  4.11631100    1.27266300    6.16601900
 N                  4.79589700   -0.75551000    6.10458000
 C                  3.84725400   -2.56905700    8.12949500
 H                  4.30097800   -1.60381800    8.36275700
 C                  3.78212100    0.04654700    5.68862400
 C                  5.31377600    1.23661400    6.86538600
 H                  5.73615800    2.11580300    7.31807300
 C                  5.74598800   -0.04353900    6.82058200
 H                  6.62307200   -0.51420200    7.22755400
 C                  4.87618400   -2.16786200    5.82849800
 C                  4.44711000   -3.06400100    6.82043600
 C                  4.12921000   -3.49211300    9.31979100
 H                  3.79672800   -3.01483400   10.24440600
 H                  5.19468600   -3.71241100    9.41800300
 H                  3.59301400   -4.43989700    9.23783400
 C                  4.52475500   -4.42367600    6.52615400
 H                  4.19502300   -5.15098600    7.25538700
 C                  5.00315700   -4.86300000    5.29804100
 H                  5.04529700   -5.92481700    5.08694500
 C                  5.41297700   -3.95259900    4.33719000
 H                  5.77029700   -4.31007300    3.37977000
 C                  5.35807400   -2.57903700    4.58053800
 C                  5.77683900   -1.59628700    3.49809200
 H                  5.68068000   -0.58615800    3.89643000
 C                  4.84424500   -1.69698900    2.28231900
 H                  4.93000900   -2.67132300    1.79610600
 H                  5.09084300   -0.93059200    1.54401100
 H                  3.79981700   -1.56916100    2.57364900
 C                  7.24394100   -1.78653700    3.08939400
 H                  7.41372300   -2.77153500    2.64887200
 H                  7.91190000   -1.68493400    3.94784700
 H                  7.53093400   -1.03782800    2.34680100
 C                  3.32669400    2.46368700    5.97957700
 C                  3.64086900    3.30850500    4.90419400
 C                  2.86443900    4.45525300    4.74556500
 H                  3.06445600    5.13037200    3.92439600
 C                  1.82556600    4.74028600    5.62223400
 H                  1.23118400    5.63455600    5.47796000
 C                  1.53514700    3.88114100    6.67053200
 H                  0.70996800    4.10899300    7.33288200
 C                  2.27926500    2.71754700    6.87318000
 C                  1.90888900    1.75479200    7.99100900
 H                  2.68655700    0.99328400    8.05891400
 C                  1.83892100    2.45246800    9.35572200
 H                  2.77338900    2.96828600    9.58898800
 H                  1.65145500    1.71982200   10.14437000
 H                  1.03223900    3.18758200    9.39472500
 C                  0.59013900    1.03561400    7.66701100
 H                 -0.23303000    1.74782700    7.57319300
 H                  0.33554400    0.32606200    8.45712500
 H                  0.65241100    0.47777300    6.73160700
 C                  4.73144400    2.95180300    3.90409700
 H                  5.43723900    2.28260600    4.39923800
 C                  5.53128100    4.16549200    3.41807100
 H                  4.92936300    4.82964900    2.79436700
 H                  6.37715700    3.83426400    2.81126200
 H                  5.92358900    4.74948900    4.25345000
 C                  4.12693800    2.18521900    2.71599600
 H                  3.61187700    1.28342600    3.04981100
 H                  4.90811600    1.88858600    2.01174900
 H                  3.40159500    2.80281900    2.18246600
 C                  2.33551300   -2.33773700    7.96591900
 H                  2.12380200   -1.62529200    7.16960700
 H                  1.90590500   -1.94853000    8.89226600
 H                  1.82346700   -3.26922300    7.71703600
 C                  0.80179200   -0.74239400    3.16507500
 H                  1.58320500   -0.28860100    2.53126500
 C                  0.65575300   -2.13651800    4.70381800
 O                  1.40923300   -3.04170700    4.46533700
 O                 -0.29967300   -1.79747900    5.34648100
 H                  0.57181700   -1.65020900    2.61543500
 C                 -0.43888700    0.15950200    3.18048600
 H                 -1.01893400   -0.03549000    4.08606400
 C                 -0.08346200    1.64276800    3.22468100
 C                 -1.38261300   -0.16226300    2.01821800
 F                  0.62358500    1.91921100    4.34181700
 F                  0.67464500    2.03491400    2.17497600
 F                 -1.16570500    2.44866000    3.24989200
 F                 -2.53960700    0.53310800    2.06231100
 F                 -0.82381600    0.07602000    0.81018000
 F                 -1.72105600   -1.47041100    2.04638700



